ISSN print edition: 0366-6352
ISSN electronic edition: 1336-9075
Registr. No.: MK SR 9/7

Published monthly
 

Refinement of the crystal structure of the dithiocyanatodiamminecopper(II) complex

J. Garaj

Slowakischen Tech. Hochsch., Bratislava

 

Abstract: The cryst. structure of the Cu(SCN)2(NH3)2 complex was studied by x-ray diffraction and least sqs. refinement. The space group is Pnma, with a 13.94 ± 0.02, b 6.01 ± 0.01, and c 8.86 ± 0.01A.; R = 0.155; Z = 4. Cu(II) is plane coordinated with 2 mols. of NH3 and 2 N atoms of the SCN group. Av. interat. distances are Cu-NH3 1.997 and Cu-N = 1.965A. The plane coordination of the central atom is completed by 2 S atoms at 3.028A. The SCN groups are bound to Cu(II) with S and N atoms.

Full paper in Portable Document Format: 2112a865.pdf (in German)

 

Chemical Papers 21 (12) 865–876 (1967)

Friday, March 29, 2024

IMPACT FACTOR 2021
2.146
SCImago Journal Rank 2021
0.365
SEARCH
Advanced
VOLUMES
European Symposium on Analytical Spectrometry ESAS 2022
© 2024 Chemical Papers