ISSN print edition: 0366-6352
ISSN electronic edition: 1336-9075
Registr. No.: MK SR 9/7
Oscillopolarography of molybdates and tungstates
E. Bodor and M. Maleczki-Szeness
Univ. Chem. Ind., Veszprem, Hung.
Abstract: In a.-c. oscillographic polarography with a dropping Hg electrode, molybdate and tungstate ions in acidic solns. gave sharp cathodic inflections on the curve dE/dt = f(E) at concns. of 10-7-10-4M, corresponding to catalytic evolution of H. When the depolarizer was present in the form of an isopolyacid, the inflections were observable at a concn. of 10-7M. At tungstate concn. ≥105M, an inverted anodic peak in the form of a sharp min. was formed at neg. potentials; this was due to catalytic H evolution.
Full paper in Portable Document Format: 164-5a280.pdf (in German)
Chemical Papers 16 (4-5) 280–284 (1962)