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Nitrate group as a ligand in coperII-complex solutions

J. Gažo

Slovak Technical University, Bratislava

 

Abstract: The formation of nitrate-copper-II complexes and the existence of polynuclear copper-II complexes with nitrate groups as the bridge in acetone was established spectrophotometrically. In acetone systems, Cu(ClO4)2.6H2O-LiNO3, CuCl2-LiNO3, and Cu(NO3)2.3H2O-LiNO3, the ratio of [CuII] to [NO3-] was 3:8, 2:1, and 1:3.

Full paper in Portable Document Format: 166a439.pdf (in Slovak)

 

Chemical Papers 16 (6) 439–448 (1962)

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