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Graphite indicator electrode for potentiometric neutralization titrations

J. Berčík

Slovak Technical University, Bratislava

 

Abstract: The behavior of graphite electrodes during neutralization titrations in aq. soln. in the presence of strong oxidn. compds. is described. A graphite electrode, with a calomel electrode, can be used for an indication of the titration curve. A graphite electrode, activated in H2O or in KMnO4 soln., acquires a linear relation between potential and pH. Because of low internal resistance, strength of the electrode, stability to oxidn. and redn., the graphite electrode can be applied even under unfavorable conditions.

Full paper in Portable Document Format: 145a372.pdf (in Slovak)

 

Chemical Papers 14 (5) 372–384 (1960)

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