ISSN print edition: 0366-6352
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Physical-chemical study and polarographic behavior of l-phenylacetylcarbinol and methylbenzoylcarbinol. I

M. Fedoro┼łko

Slovak Academy of Sciences, Bratislava

 

Abstract: The polarographic behavior of l-phenylacetylcarbinol and methylbenzoylcarbinol is described. The effect of various cations on half-wave potentials of I was detd. The shift Ε1/2 of I to the pos. values is dependent on the type of cation and its concn., and it increases in this order: Na+ < K+ < Li+ < Ca2+ < CH3NH3+ < NH4+. Both of the compds. studied are subjected on the drop electrode to double-electron irreversible reduction.

Full paper in Portable Document Format: 121a17.pdf (in Slovak)

 

Chemical Papers 12 (1) 17–23 (1958)

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