ISSN print edition: 0366-6352
ISSN electronic edition: 1336-9075
Registr. No.: MK SR 9/7

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Claisen rearrangement of m-allyloxytoluene

L. Dúbravková, I. Ježo, P. Šefčovič, and Z. Votický

Slovak Academy of Sciences, Bratislava

 

Abstract: By Claisen rearrangement of m-allyloxytoluene are formed 3,2-, 5,2-, and 3,4-Me(CH2:CHCH2)C6H3OH, which can be detd. chromatographically in the phenol mixt. and by detg. the m.ps. of oxidation products and the m.ps. of the mixt. with authentic compds. For oxidation, a mixt. of x,3-Pr(MeO)C6H3Me were formed from x-allyl-3-methylphenols by methylation and hydrogenation.

Full paper in Portable Document Format: 121a24.pdf (in Slovak)

 

Chemical Papers 12 (1) 24–28 (1958)

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