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Polymerization of tetrasubstituted allylmethylsilanes. II. The mechanism of radical polymerization of allyltrimethylsilane

D. Mikulášová and A. Hrivík

Slovak Technical University, Bratislava

 

Abstract: cf. C.A. 52, 9028b. A method for the detn. of tert-BuOH (I) in the polymerization system is described. It was proven that at the polymerization of CH2:CHCH2SiMe3 (II) at 140° there is a side reaction with the formation of I which participates on the av. to the extent of 24.6% of the total conversion. The mechanism of radical polymerization of II is discussed. The calcd. kinetic relations are in agreement with the exptl. results.

Full paper in Portable Document Format: 1112a708.pdf (in Slovak)

 

Chemical Papers 11 (12) 708–714 (1957)

Tuesday, May 21, 2024

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