ISSN print edition: 0366-6352
ISSN electronic edition: 1336-9075
Registr. No.: MK SR 9/7
Rapid preparation o-nitroaniline and o-phenylenediamine
Slovak Technical University,
Abstract: By modifying some conditions during the prepn. from AcNHPh and refluxing by superheated H2O in vacuo, o-nitroaniline (I), m. 72.5°, was obtained in 60.0-3.4% yield and the time of prepn. was shortened to 12 hrs. From I by reduction with H and with Raney Ni as catalyst was obtained 90-5% o-C6H4(NH2)2, m. 103°.
Full paper in Portable Document Format: 24a114.pdf (in Slovak)
Chemical Papers 2 (4) 114–119 (1948)