ISSN print edition: 0366-6352
ISSN electronic edition: 1336-9075
Registr. No.: MK SR 9/7

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Molecular compounds of carboxylic acids with monohydric alcohols, indicated by means of the Ulehla osmometer I

B. Stehlík

Slovak Technical University, Bratislava

 

Abstract: Curves connecting velocity of osmosis with mol. compn. of the binary systems exhibit well-defined min., suggesting formation of the mol. compds.: HCO2H.3MeOH; AcOH.3MeOH; HOCH2CO2H.4MeOH; (CO2H)2.6BuOH; (CH2CO2H)2.6MeOH; [CH(OH)CO2H]2.8BuOH; and citric acid -10MeOH. In general, the no. of mols. of alc. in the compds. is equal to the no. of OH groups in the acids, regarding CO2H as C(OH)3.

Full paper in Portable Document Format: 14a97.pdf (in Slovak)

 

Chemical Papers 1 (4) 97–110 (1947)

Saturday, September 19, 2020

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