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Kinetics of alkaline hydrolysis of the monomethyl ester of terephthalic acid in mixed aqueous-organic solvents

V. Holba and J. Benko and

Department of Physical Chemistry, Faculty of Natural Sciences, Komensk√Ĺ University, CS-842 15 Bratislava

 

Abstract: The kinetics of alkaline hydrolysis of the monomethyl ester of terephthalic acid was investigated in aqueous and mixed aqueous-nonaqueous media. The experimental results are appreciated from the view-point of the influence of ionic strength and relative permittivity of the solvent on kinetic parameters. A significant influence of specific interactions of supporting electrolytes and nonaqueous cosolvents on the reaction has been revealed.

Full paper in Portable Document Format: 392a207.pdf

 

Chemical Papers 39 (2) 207–216 (1985)

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