ISSN print edition: 0366-6352
ISSN electronic edition: 1336-9075
Registr. No.: MK SR 9/7
Kinetics of alkaline hydrolysis of the monomethyl ester
of terephthalic acid in mixed aqueous-organic solvents
V. Holba and J. Benko and
Department of Physical Chemistry, Faculty of Natural Sciences,
Komenský University, CS-842 15 Bratislava
Abstract: The kinetics of alkaline hydrolysis of the monomethyl ester of terephthalic
acid was investigated in aqueous and mixed aqueous-nonaqueous media. The
experimental results are appreciated from the view-point of the influence of
ionic strength and relative permittivity of the solvent on kinetic parameters.
A significant influence of specific interactions of supporting electrolytes and
nonaqueous cosolvents on the reaction has been revealed.
Full paper in Portable Document Format: 392a207.pdf
Chemical Papers 39 (2) 207–216 (1985)