ISSN print edition: 0366-6352
ISSN electronic edition: 1336-9075
Registr. No.: MK SR 9/7
Study of Fe-doped V2O5/TiO2 catalyst for an enhanced NH3-SCR in diesel exhaust aftertreatment
Li-Cheng Wu, Qian Wang, Wei Zhao, and Emmanuel K. Payne
Jiangsu University, Zhenjiang, China
Abstract: Selective catalytic reduction (SCR) with ammonia has been considered as the most promising technology, as its effect deals with the NOX. Novel Fe-doped V2O5/TiO2 catalysts were prepared by sol–gel and impregnation methods. The effects of iron content and reaction temperature on the catalyst SCR reaction activity were explored by a test device, the results of which revealed that catalysts could exhibit the best catalytic activity when the iron mass ratio was 0.05%. It further proved that the VTiFe (0.05%) catalyst performed the best in denitration and its NOX conversion reached 99.5% at 270 °C. The outcome of experimental procedures: Brunauer–Emmett–Teller surface area, X-ray powder diffraction, transmission electron microscopy, X-ray photoelectron spectroscopy, temperature-programmed reduction and adsorption (H2-TPR, NH3-TPD) techniques showed that the iron existed in the form of Fe3+ and Fe2+ and the superior catalytic performance was attributed to the highly dispersed active species, lots of surface acid sites and absorbed oxygen. The modified Fe-doped catalysts do not only have terrific SCR activities, but also a rather broad range of active temperature which also enhances the resistance to SO2 and H2O.
Keywords: Fe doping ; SCR ; V2O5/TiO2
Full paper is available at www.springerlink.com.
Chemical Papers 72 (8) 1981–1989 (2018)