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Stereoselective synthesis of the polar part of mycestericins E and G

Miroslava Martinková, Jozef Gonda, Alena Uhríková, and Margaréta Kováčvá

Department of Organic Chemistry, Institute of Chemical Sciences, P. J. Šafárik University, Moyzesova 11, 040 01 Košice, Slovakia

 

E-mail: miroslava.martinkova@upjs.sk

Abstract: 5-O-(t-Butyldimethylsilyl)-3-deoxy-3-C-hydroxymethyl-1,2-O-isopropylidene-3-(methoxycarbonylamino)-α-d-xylofuranose IV has been proved to be an appropriate building block in the stereoselective synthesis of methyl (4S)-4-[(1′R)-1′-acetoxy-4′-oxobutyl]-3-benzyl-2-oxooxazolidine-4-carboxylate III representing the polar part of the naturally occurring mycestericins E and mycestericins G.

Keywords: mycestericins – α-amino acid – stereoselective synthesis – immunosuppressant

Full paper is available at www.springerlink.com.

DOI: 10.2478/s11696-011-0030-5

 

Chemical Papers 65 (4) 527–535 (2011)

Wednesday, August 10, 2022

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