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ISSN print edition: 0366-6352
ISSN electronic edition: 1336-9075
Registr. No.: MK SR 9/7
Published monthly
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Enthalpies of solution of methoxy and ethoxy end group oligomers of poly(ethylene glycol) in binary solvent water - dimethylformamide Study of hydrophobic hydration
P. Cifra and A. Romanov
Polymer Institute, Centre for Chemical Research, Slovak Academy of Sciences,
CS-84236 Bratislava
Abstract: Deviations from ideality in solution enthalpies of solutes are explained by hydrophobic hydration. The extent of this type of hydration is expressed by means of two methods. Experimental results obey previously proposed group contribution concept for evaluation of enthalpic effect of hydropho bic hydration and the obtained methylene group contribution is in good agreement with that obtained previously from the data on other hydrophobic homologous series.
Full paper in Portable Document Format: 413a395.pdf
Chemical Papers 41 (3) 395–400 (1987)
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