ISSN print edition: 0366-6352 ISSN electronic edition: 1336-9075 Registr. No.: MK SR 9/7 Published monthly

Electrochemical study of the diethyldithiocarbamate anion and of its oxidation products

J. Labuda, J. Mocák, and D. I Bustin

Department of Analytical Chemistry, Slovak Technical University, 812 37 Bratislava

Abstract:  Study has been made of the voltammetric behaviour of the diethyldithiocarbamate anion, tetraethylthiuram disulfide, tetramethylthiuram monosulfide, sulfur, sodium sulfide, and of tetramethylthiourea on a platinum and mercury electrodes in acetonitrile and dimethylformamide. Findings have been supplemented by coulometric electrolysis results. A mechanism of processes of a deeper electrode oxidation of dithiocarbamates has been suggested and discussed.

Full paper in Portable Document Format: 365a633.pdf

Chemical Papers 36 (5) 633–642 (1982)