ISSN print edition: 0366-6352 ISSN electronic edition: 1336-9075 Registr. No.: MK SR 9/7 Published monthly

Oscillographic polarography of organic compounds in anhydrous NH4NO3nNH3

J. Matysik

Marie Curie-Sklodowska Univ., Lublin, Pol.

Abstract: In a.-c. oscillographic polarography with a dropping Hg electrode, a liquid mixt. of anhyd. NH₄NO₃ and NH₃ at 0-20° was used as supporting electrolyte. Characteristic inflections on the curve dE/dt = f(E) were obtained with org. (nitro compds., quinones, ketones, aldehydes, alkaloids) as well as inorg. compds. Quinones gave 2 reversible inflections, while the corresponding hydroquinones were inactive. Papaverine, morphine, and benzidine gave inflections which were capacitive in nature. The behavior of metal cations was similar to that in aq. solns.

Full paper in Portable Document Format: 164-5a311.pdf (in German)

Chemical Papers 16 (4-5) 311–315 (1962)