ISSN print edition: 0366-6352 ISSN electronic edition: 1336-9075 Registr. No.: MK SR 9/7 Published monthly

Innersphere redox reactions of iron(II) halogeno complexes containing π-acceptor ligands

J. Šima, A. Šimová, and T. Hledíková

Department of Inorganic Chemistry, Slovak Technical University, CS-812 37 Bratislava

Abstract: The paper presents the results of the study of spontaneous redox reactions occurring in the systems of Fe(II) iodo complexes in acetone. The influence of halogenide, pseudohalogenide, and ligands of σ-donor and π-acceptor ability on the formation of conditions for innercomplex redox reactions of high-spin Fe(II) complexes containing the above-mentioned ligands is discussed. The results are interpreted on the basis of the phenomenon of the mutual influence of ligands through the central atom.

Full paper in Portable Document Format: 391a41.pdf

Chemical Papers 39 (1) 41–47 (1985)